Basically, there are five identified key categories of CO2-derived production processes and services that are attracting global interest. The analysis Can give the technical aspect of all of these applications that could be scaled up but facing commercial and regulatory barriers.
- CO2 - derived fuels
The carbon in CO2 can produce fuels that are
in use today, including methane, methanol, gasoline, and aviation fuels. The
process involves hydrogen; the combination of hydrogen is highly
energy-intensive to produce and gives a carbon-containing fuel that is easier
to handle. Low-carbon hydrogen can be made from fossil fuels when combined with
CCS or through electrolysis of water using low carbon electricity (IEA,
2019b). CO2 -derived fuels are particularly interesting for
applications where the use of other low-carbon energy carriers, such as
electricity or hydrogen, is exceptionally challenging, such as in aviation.
There are already few firms that have built demonstration and pilot plants
producing methane and methanol from CO2 and hydrogen, together with
using hundreds to thousands of tonnes of CO2 per year. Other
chemical and biological conversion pathways to make CO2 -derived
fuels are in the early research or demonstration stages.
From carbon dioxide, Estimated production costs of
methanol and methane in most world regions are currently more than 2 to 7 times
higher as compared to the fossil counterparts. The main cost factor is
typically electricity, accounting for between 40-70% of the production costs.
Hence, small average grid electricity prices are required for CO2
-derived methane and methanol to be competitive. Direct use of low carbon
hydrogen and electricity as fuel will be a more cost-effective option in most
cases under these conditions. Commercial production of CO2 -derived
methane and methanol could be possible in the global market where there is both
low-cost renewable energy and CO2 are available.
For example, the George Olah facility in Iceland Converting around 5,600 tonnes of CO2 / year into methanol with hydrogen produced from renewable electricity.
2.
CO2 -derived chemicals
The carbon present (and oxygen) in CO2 can
be used as an alternative to fossil fuels in producing chemicals, including
plastics, fibers, and synthetic rubber. As with CO2 -derived fuels,
converting CO2 to methanol and methane is the most technologically
mature pathway. The methanol can be converted into other carbon-containing
high-value chemical intermediates like olefins, which are generally used for
manufacturing plastics and aromatics, and are used in various sectors,
including health and hygiene products and processing.
A particular group of chemicals, polymers, are used to
produce plastics, foams, and resins. The carbon contained in CO2 can
be used in polymer production part replacement of the fossil fuel-based raw
material in the manufacturing process. Unlike the conversion of Carbon dioxide
to fuels and chemical intermediates, this polymer processing with CO2
requires little energy input Due to the conversion of CO2 into a
molecule with an even lower energy state (carbonate). Several companies are
currently operating polymer plants using CO2 as a raw material.
Polymer processing with CO2 is going to be competitive in the market due to the relatively low energy required for their production and high market value. Some claim that specific polymers can be made at 15% to 30% lower cost as compared to fossil counterparts provided the CO2 used is cheaper than the fossil fuels-based raw material it replaces (von der Assen, 2015). Like CO2 CO2 -derived fuels and chemicals, further compliance testing is needed before polymers with high mass percentages of CO2 can enter the market.
3. Building
materials from minerals and CO2
Building materials from minerals and CO2 Carbon
dioxide can produce building materials to replace the water in concrete, known
as CO2 curing, or raw material like cement and construction
aggregates. These applications involve the reaction of CO2 with
calcium or magnesium to form low-energy carbonate molecules, the structure of
carbon that makes up concrete. The most mature and Effective application of CO2
is the use of CO2-cured concrete, while in the earlier stage of
development, the integration of CO2 in the production of cement
itself. CO2 -cured concrete can have superior performance, lower
manufacturing costs, and a lower CO2 footprint than conventionally
produced concrete.
4.
Building materials from waste and CO2
CO2 -cured concrete can have superior
performance, lower manufacturing costs, and a lower CO2 footprint
than conventionally produced concrete. Although the CO2 footprint of
concrete can be reduced by around 80%, these claims have not been verified
independently (CarbonCure, 2019). A highly perspective opportunity for early
application of these technologies is the market for pre-cast concrete products
and ready-mixed concrete cured with CO2 and water at the plant
before being transported for use in construction. A shift from prescriptive to
performance-based progress could facilitate the uptake of novel CO2
-derived building materials.
5.
Crop yield boosting with CO2
CO2 can enhance yields of crop production,
like algae production and crop cultivation under greenhouses. Low-temperature
heat in industrial greenhouses with the application of CO2 can increase
yield by 25% to 30% and mature yield - boosting application today. The clear
leader in using CO2 in greenhouses is the Netherlands, with an estimated annual
consumption of between 5 and 6.3 Mt CO2. Of this amount,
approximately 500 kt CO2 per year comes from external sources,
mainly industrial plants. The replacement of these on-site systems (balance
taken from on-site gas-fired boilers or co-generation systems) with other
industrial CO2 sources or CO2 captured directly from the
atmosphere could deliver climate benefits.
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